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MOF heterojunctions 1

UiO-66/MoSe2 1

bandgap 1

dye-containing wastewater 1

electrospinning 1

heavy metal wastewater 1

heterojunctions 1

lignin 1

materials derived from MOFs 1

metal–organic frameworks (MOFs) 1

oxygen vacancies 1

photo-Fenton catalysis 1

photocatalysis 1

photocatalytic hydrogen evolution 1

recombination 1

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Lignin-based electrospun nanofiber membrane decorated with photo-Fenton Ag@MIF-100(Fe) heterojunctions

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 7,   Pages 930-941 doi: 10.1007/s11705-023-2309-9

Abstract: fabricate a lignin-based electrospun nanofiber membrane (LENM) decorated with photo-Fenton Ag@MIL-100(Fe) heterojunctions

Keywords: lignin     electrospinning     heterojunctions     photo-Fenton catalysis     wastewater remediation    

Construction of defect-containing UiO-66/MoSe heterojunctions with superior photocatalytic performance

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 4,   Pages 449-459 doi: 10.1007/s11705-022-2226-3

Abstract: Metal–organic frameworks are recognized as promising multifunctional materials, especially metal–organic framework-based photocatalysts, which are considered to be ideal photocatalytic materials. Herein, a new type of UiO-66/MoSe2 composite was prepared using the solvothermal method. The optimum composite was selected by adjusting the mass ratio of UiO-66 and MoSe2. X-ray diffraction analysis showed that the mass ratio influenced the crystal plane exposure rate of the composite, which may have affected its photocatalytic performance. The composite is composed of ultra-thin flower-like MoSe2 that wrapped around cubic UiO-66, a structure that increases the abundance of active sites for reactions and is more conducive to the separation of carriers. The photocatalytic properties of the composite were evaluated by measuring the degradation rate of Rhodamine B and the catalyst’s ability to reduce Cr(VI)-containing wastewater under visible light irradiation. Rhodamine B was decolorized completely in 120 min, and most of the Cr(VI) was reduced within 150 min. The photochemical mechanism of the complex was studied in detail. The existence of Mo6+ and oxygen vacancies, in addition to the Z-type heterojunction promote the separation of electrons and holes, which enhances the photocatalytic effect.

Keywords: UiO-66/MoSe2     photocatalysis     dye-containing wastewater     heavy metal wastewater     oxygen vacancies    

Novel strategies to tailor the photocatalytic activity of metal–organic frameworks for hydrogen generation: a mini-review

Luis A. ALFONSO-HERRERA, Leticia M. TORRES-MARTINEZ, J. Manuel MORA-HERNANDEZ

Frontiers in Energy 2022, Volume 16, Issue 5,   Pages 734-746 doi: 10.1007/s11708-022-0840-x

Abstract: strategies: tailoring the photocatalytic activity of bare MOFs and guest@MOF composites, formation of heterojunctions

Keywords: metal–organic frameworks (MOFs)     photocatalytic hydrogen evolution     MOF heterojunctions     materials derived    

Title Author Date Type Operation

Lignin-based electrospun nanofiber membrane decorated with photo-Fenton Ag@MIF-100(Fe) heterojunctions

Journal Article

Construction of defect-containing UiO-66/MoSe heterojunctions with superior photocatalytic performance

Journal Article

Novel strategies to tailor the photocatalytic activity of metal–organic frameworks for hydrogen generation: a mini-review

Luis A. ALFONSO-HERRERA, Leticia M. TORRES-MARTINEZ, J. Manuel MORA-HERNANDEZ

Journal Article